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Sodium Nickel Iron Manganese Layered Oxide Cathode Material for Sodium Ion Batteries

Battery powder materials

Sodium Nickel Iron Manganese Layered Oxide Cathode Material for Sodium Ion Batteries

Item Number : CL12

Price varies based on specs and customizations


Gram Specific Capacity
≥120.0 mAh/g (127 mAh/g typical)
Tap Density
≥1.20 g/cm³ (1.34 g/cm³ typical)
Particle Size (D50)
8.00 ± 2.00 µm (7.64 µm typical)
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Product Overview

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This high-performance sodium nickel iron manganese layered oxide cathode powder represents a cutting-edge active material engineered specifically for next-generation sodium-ion battery cell development and large-scale energy storage systems. Formulated with a optimized stoichiometry of sodium, iron, manganese, and nickel elements, this system delivers an excellent balance of high specific discharge capacity (≥120.0 mAh/g target, 127 mAh/g typical at 0.1C), elevated tap density (1.34 g/cm³ typical), and low residual surface alkali content. Its optimized layered crystal architecture promotes rapid sodium-ion transport kinetics while suppressing adverse phase transformations during extended electrochemical cycling.

Designed for integration into full commercial cell manufacturing workflows, the material exhibits exceptional slurry compatibility, predictable rheological behavior, and high operational stability across coin cells, 18650 cylindrical cells, and pouch cell configurations. Target applications span stationary grid energy storage, industrial power backup modules, low-speed electric mobility units, and academic energy material R&D. The balanced chemical composition avoids reliance on scarce or costly cobalt and high nickel concentrations, ensuring an economically sustainable raw material footprint.

Manufactured under stringent quality control protocols, this unit undergoes comprehensive chemical and physical validation to guarantee consistent batch-to-batch repeatability. With rigorous monitoring of moisture content (≤500 ppm target, 432 ppm typical), particle size distribution (D50 of 7.64 µm), and surface residual carbonate/hydroxide levels, the material minimizes gelation risks during slurry preparation and ensures long-term operational integrity under demanding charge-discharge regimes and ambient moisture conditions.

Key Features

  • High Gram Discharge Capacity: Delivers a certified discharge capacity of ≥120.0 mAh/g (typical value of 127 mAh/g) when tested in button half-cells within a 2.0V to 4.0V voltage window at 0.1C, offering high volumetric and gravimetric energy density.
  • Superior High-Rate Discharge Kinetic Performance: Demonstrates exceptional rate capability in 18650 cylindrical test cells, retaining 106.40% capacity at 0.2C, 103.20% at 0.5C, 98.40% at 2.0C, 96.33% at 3.0C, 94.45% at 4.0C, and 91.58% at an ultra-high 5.0C discharge rate relative to the 1.0C baseline.
  • Outstanding Low-Temperature Discharge Retention: Maintains high energy output under extreme environmental conditions, retaining 91.58% of room-temperature capacity at -10°C and 87.89% capacity at -20°C in full-cell testing protocols.
  • Controlled Particle Morphometry & High Tap Density: Engineered with a tightly controlled particle size distribution (D10 ≥ 2.0 µm, D50 = 8.00 ± 2.00 µm, D90 ≤ 24.00 µm) and a high tap density of 1.34 g/cm³, ensuring optimal packing density during electrode calendering and pressing.
  • Low Residual Surface Alkali: Features strict chemical limits on remnant sodium carbonate (Na2CO3) and sodium hydroxide (NaOH) surface species, maintaining a controlled pH of 12.82 (≤13.00 specification) to prevent slurry gelling and binder cross-linking during cathode preparation.
  • Stable Slurry Processing Behavior: Formulated for high solid-content cathode slurries (up to 53% solid loading with 95.5% active material content), exhibiting controlled viscosity progression from 3540 mPa·s initially to 6820 mPa·s over 24 hours under 7% relative humidity.
  • Controlled Environmental Moisture Sensitivity: Maintains capacity stability without electrochemical decay when processed under controlled atmospheric moisture conditions (7% RH for up to 5 hours), ensuring reliable pilot-scale and commercial electrode coating operations.
  • Balanced Chemical Composition: Leverages abundant sodium, iron, manganese, and nickel elements (Na + Fe + Mn content of 50.50 ± 1.00 wt%) to lower overall cell manufacturing costs while ensuring environmental compliance and supply chain security.

Applications

Application Description Key Benefit
Stationary Grid Energy Storage Large-scale battery energy storage systems (BESS) for renewable energy integration and grid frequency regulation. Low material cost combined with long cycle stability and safe thermal characteristics under continuous operation.
Industrial Cylindrical Cell Fabrication Commercial 18650 and 21700 cell production lines for industrial power tools and uninterruptible power supplies (UPS). Excellent tap density (1.34 g/cm³) and smooth slurry coating characteristics enable uniform high-speed electrode manufacturing.
Low-Temperature & Harsh Environment Power Battery modules operating in arctic conditions, cold-chain logistics, and unheated outdoor installations. Exceptional low-temperature capacity retention (87.89% at -20°C) ensures dependable power delivery in extreme climates.
High-Rate Electric Mobility Power packs for two/three-wheel electric vehicles, low-speed EVs, and automated guided vehicles (AGVs). Maintains over 91.58% capacity retention at high 5.0C discharge rates, supporting rapid acceleration and fast power delivery.
Advanced Sodium-Ion Battery Research Academic and corporate R&D laboratories developing next-generation sodium chemistries and electrolyte formulations. Highly consistent physical specifications and low residual alkali provide repeatable baseline metrics for coin and pouch cell testing.

Technical Specifications

Material Model Identifier: CL12

Specification Parameter Unit Target Specification Indicator Typical Value Test Method / Instrument
Product Identifier - CL12 CL12 Standardized Material Code
Appearance - Black Powder Black Powder Visual Inspection (目测)
Tap Density (振实密度) g/cm³ ≥ 1.20 1.34 GB/T 5162-2006
Specific Surface Area (比表面积) m²/g 0.3 - 1.0 0.68 BET Specific Surface Analyzer (比表面仪)
Moisture Content (H2O) ppm ≤ 500 432 Moisture Analyzer (水分仪)
Particle Size D10 µm ≥ 2.0 3.45 Laser Particle Size Analyzer (激光粒度仪)
Particle Size D50 µm 8.00 ± 2.00 7.64 Laser Particle Size Analyzer (激光粒度仪)
Particle Size D90 µm ≤ 24.00 17.03 Laser Particle Size Analyzer (激光粒度仪)
Sodium (Na) Content wt% 20.50 - 21.00 20.72 Atomic Absorption Spectroscopy (AAS)
Combined Na + Fe + Mn Content wt% 50.50 ± 1.00 50.63 GB/T 1223.25-1994 Gravimetric Method
Slurry pH - ≤ 13.00 12.82 pH Meter (PG计)
Discharge Specific Capacity (克比容量) mAh/g ≥ 120.0 127 Coin Half-Cell, 4.0V–2.0V, 0.1C Discharge

Rate Capability Performance (18650 Cell, Voltage Window: 2.0V–4.0V, Test Temp: 25 ± 2°C)

C-Rate Discharge Current Relative Capacity (%) Electrochemical Transport Characteristics
0.2C 106.40% Maximum sodium-ion de-intercalation efficiency
0.5C 103.20% High energy extraction under moderate loads
1.0C 100.00% Reference capacity baseline
2.0C 98.40% Minimal polarization voltage drop
3.0C 96.33% Sustained fast-discharge power output
4.0C 94.45% Outstanding high-power retention
5.0C 91.58% Excellent ultra-high rate capability

Low-Temperature Discharge Characteristics (18650 Cell, Voltage Window: 2.0V–4.0V)

Operating Temperature (°C) Capacity Retention Ratio (%) Environmental Performance Profile
25°C 100.00% Ambient baseline capacity
-10°C 91.58% Superior low-temperature ion diffusion
-20°C 87.89% Robust operation under sub-zero conditions

Slurry Rheology & Environmental Exposure Parameters

Parameter / Condition Standard Value / Metric Operational Notes
Cathode Slurry Formulation Ratio Active Material : SP : CNT : PVDF(5130) = 95.5 : 1.7 : 0.8 : 2.0 Optimized high-active mass fraction formulation
Slurry Solid Content 53% Suitable for commercial industrial roll-to-roll coaters
Slurry Viscosity (Initial) 3540 mPa·s Tested under 7% Relative Humidity (RH)
Slurry Viscosity (3 Hours) 4430 mPa·s Stable viscosity growth profile
Slurry Viscosity (12 Hours) 6020 mPa·s Controlled rheology over extended pot life
Slurry Viscosity (24 Hours) 6820 mPa·s Prevents rapid phase separation or severe gelling
Environmental Exposure Resilience 7% RH for 5 hours exposure Controlled moisture uptake; capacity does not decay

Why Choose This Product

  • Proven Batch-to-Batch Consistency: Rigorous quality control protocols ensure tight particle size distributions (D50 = 8.00 ± 2.00 µm) and consistent chemical composition for seamless cell manufacturing scale-up.
  • Exceptional Electrochemical Kinetic Stability: Delivers market-leading rate performance (91.58% capacity retention at 5.0C) and low-temperature tolerance (87.89% retention at -20°C), widening the operational window of finished battery packs.
  • Engineered Surface Chemistry: Low residual alkali levels (pH 12.82) drastically reduce slurry gelling risk, enabling high solid content (53%) coating mixes and extended slurry pot life in production environments.
  • Comprehensive Material & Process Validation: Supported by extensive empirical test data across coin half-cells and full 18650 cylindrical cell formats to accelerate your R&D and pilot line integration.
  • End-to-End Battery Workflow Integration: Positioned alongside our complete laboratory pressing, slurry mixing, coating, and testing equipment portfolio to provide a total solution for advanced materials research.

Contact our technical sales engineering team today to request detailed specification sheets, order validation samples, or discuss customized sodium-ion material processing solutions tailored to your cell development pipeline.

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Sodium Nickel Iron Manganese Layered Oxide Cathode Material for Sodium Ion Batteries

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