Battery supporting materials
LiTFSI Lithium Bis Trifluoromethanesulfonyl Imide Electrolyte for Lithium Sulfur Battery Applications
Item Number : FZ51
Price varies based on specs and customizations
- Lithium Salt Concentration
- 1.0 M LiTFSI
- Solvent Formulation
- DME : DOL (1:1 Volume Ratio)
- Functional Additive
- 1.0 wt% LiNO3 (Optional)
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Product Overview


This high-purity battery electrolyte is specifically formulated for lithium-sulfur (Li-S) and next-generation lithium metal battery research. Composed of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) dissolved in a precision-blended binary ether solvent mixture of 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL), this chemical solution provides the ideal solvating environment for complex sulfur cathode electrochemistry. The specialized formulation promotes high lithium-ion mobility and suppresses excessive concentration polarization during charge-discharge cycling.
Engineered to address the fundamental challenges of sulfur utilization and polysulfide intermediate dynamics, this electrolyte system is essential for electrochemical laboratories, academic research centers, and energy storage pilot lines. The baseline ether solvent composition provides the required dielectric constant and low viscosity to facilitate rapid ion transport across porous sulfur-carbon composite electrodes and separators.
Manufactured under stringent moisture-controlled protocols, this liquid electrolyte guarantees exceptional reproducibility across coin cells, split test cells, and multi-layer pouch cells. To maintain optimal electrochemical properties and prevent ambient moisture contamination, all handling and cell fabrication operations must be conducted strictly within vacuum, dry room, or inert-gas glovebox environments.
Key Features
- Superior Anion Delocalization and Ion Dissociation: The large, flexible bistriflimide anion [N(SO2CF3)2]− features extensive negative charge delocalization across its sulfonyl groups, effectively reducing ion-pairing tendencies and delivering remarkably high lithium cation transference numbers compared to conventional inorganic lithium salts.
- Optimized Binary Ether Solvent Matrix: The 1:1 volumetric blend of 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL) combines high polysulfide solubility with low bulk viscosity, facilitating rapid wetting of thick cathode structures and lowering interfacial charge-transfer resistance.
- Effective Lithium Anode Passivation: Available with standard 1 wt% lithium nitrate (LiNO3) additive, this formulation promotes the formation of a robust, protective solid electrolyte interphase (SEI) on metallic lithium anodes, effectively suppressing the parasitic polysulfide shuttle effect and extending cell cycle life.
- Enhanced Thermal and Electrochemical Stability: Unlike legacy salts such as LiClO4 or LiAsF6, this imide salt structure exhibits exceptional resistance to thermal degradation and oxidative decomposition, ensuring stable operation across standard Li-S operating voltage windows.
- Reduced High-Rate Polarization: The combination of elevated ionic conductivity and low ionic association minimizes concentration gradients across the inter-electrode gap, allowing high-rate cycling without premature voltage cutoff in demanding test protocols.
- Ultra-Low Trace Moisture Content: Prepared under strictly controlled dry conditions, the solution maintains trace water and impurity levels below critical detection thresholds to prevent premature lithium foil corrosion and active material degradation.
- Flexible Tailored Formulations: Available in standard optimized concentrations or fully customizable ratios, allowing battery researchers to adjust salt molarity, ether proportions, and additive chemistries to target specific electro-catalytic, low-temperature, or high-areal-capacity benchmarks.
Applications
| Application | Description | Key Benefit |
|---|---|---|
| Lithium-Sulfur (Li-S) Coin Cell Testing | Baseline electrolyte for evaluating novel sulfur-carbon composite cathodes, sulfurized polyacrylonitrile (SPAN), and functional separator coatings in CR2032/CR2016 architectures. | Maximizes active sulfur conversion kinetics and provides reproducible Coulombic efficiency data. |
| Lithium Metal Anode Interphase Research | Investigation of symmetric Li|Li and asymmetric Li|Cu stripping/plating overpotentials and dendrite morphology under ether-based solvation. | Forms a stable, uniform passivating SEI that minimizes continuous electrolyte consumption. |
| Polysulfide Shuttle Mitigation Studies | Quantitative analysis of intermediate lithium polysulfide (Li2Sx) dissolution, migration, and retention mechanisms in liquid-cell configurations. | High solvent compatibility enables accurate bench testing of physical polysulfide-trapping barrier layers. |
| Multi-Layer Pouch Cell Assembly | Scaled evaluation of free-standing sulfur cathodes and ultra-thin lithium metal foils under uniform stack pressures in prototype pouch cells. | Low surface tension ensures thorough electrolyte penetration and complete separator wetting across large electrode areas. |
| In-Situ Electrochemical Characterization | Liquid medium for operando UV-Vis, Raman spectroscopy, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV) during redox reactions. | Minimizes background spectral interference and provides stable baseline response across cyclic scans. |
| Solid-Liquid Hybrid Cell Interfacial Wetting | Interfacial modifying agent applied between solid-state electrolyte membranes and porous composite cathodes to eliminate high contact resistance. | Bridges solid-solid interfacial voids, facilitating smooth Li-ion transport across hybrid cell architectures. |
Technical Specifications
| Specification Parameter | Standard Formulation (FZ51-A) | Passivated Formulation (FZ51-B) | Custom Formulation (FZ51-C) |
|---|---|---|---|
| Product Item Number | FZ51-A | FZ51-B | FZ51-C |
| Main Lithium Salt | Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) | Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) | LiTFSI / Specified Lithium Salts |
| Salt Concentration | 1.0 M (mol/L) | 1.0 M (mol/L) | 0.5 M – 2.0 M (Customizable) |
| Solvent Composition | 1,2-Dimethoxyethane (DME) : 1,3-Dioxolane (DOL) | 1,2-Dimethoxyethane (DME) : 1,3-Dioxolane (DOL) | DME:DOL or Alternate Ether/Carbonate Solvents |
| Solvent Ratio | 1:1 Volume Ratio (V%) | 1:1 Volume Ratio (V%) | Customizable Volumetric/Weight Ratios |
| Functional Additives | None | 1.0 wt% Lithium Nitrate (LiNO3) | LiNO3 / Film-Forming Additives per Requirement |
| Electrochemical Window | 0.0 V – 3.0 V vs. Li/Li⁺ (Li-S Typical) | 0.0 V – 3.0 V vs. Li/Li⁺ (Li-S Typical) | Dependent on Custom Matrix Composition |
| Moisture Content (H₂O) | ≤ 20 ppm | ≤ 20 ppm | ≤ 10 – 20 ppm (Ultra-Dry Standard) |
| Current Collector Compatibility | Carbon-coated Al / Nickel / Stainless Steel | Carbon-coated Al / Nickel / Stainless Steel | Substrate-dependent Configuration |
| Operating Environment | Inert Gas Glovebox / Dry Atmosphere | Inert Gas Glovebox / Dry Atmosphere | Inert Gas Glovebox / Dry Atmosphere |
| Storage Conditions | Sealed airtight under Ar/N₂, cool & dry space | Sealed airtight under Ar/N₂, cool & dry space | Sealed airtight under Ar/N₂, cool & dry space |
| Packaging Options | 100 mL / 250 mL / 500 mL / 1 L Bottles | 100 mL / 250 mL / 500 mL / 1 L Bottles | Research Scale to Pilot Bulk Volumes |
Why Choose This Product
- Consistent High-Purity Synthesis: Each batch undergoes rigorous dehydration and purification processes to guarantee minimal trace water and ionic impurities, preventing unpredictable cell polarization and premature side reactions.
- Engineered Specifically for Sulfur Redox Systems: The balanced DME:DOL formulation maximizes sulfur utilization by establishing an optimal equilibrium between polysulfide dissolution for active conversion and viscosity control for high ionic throughput.
- Proven Anode Compatibility: Inclusion of precisely measured LiNO3 additive passivates the lithium metal substrate, enabling dependable cycle life testing and mitigating hazardous dendritic growth.
- Flexible Custom Batch Formulation: Our chemical formulation capabilities accommodate customized molarities, solvent ratios, and functional additive packages tailored to specialized research parameters.
Contact our technical team today to request a quote or discuss tailored electrolyte formulations for your advanced battery research projects.
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Product Datasheet
LiTFSI Lithium Bis Trifluoromethanesulfonyl Imide Electrolyte for Lithium Sulfur Battery Applications
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