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Polyvinylidene Fluoride PVDF Powder Lithium Battery Cathode Binder

Battery powder materials

Polyvinylidene Fluoride PVDF Powder Lithium Battery Cathode Binder

Item Number : CL33

Price varies based on specs and customizations


Density
1.78 g/cm³ (ISO 1183)
Thermal Stability (TGA 1% Loss)
375 - 400 °C
Water Absorption (24 h at 23°C)
< 0.04% (ISO 62)
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Product Overview

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This high-purity polyvinylidene fluoride (PVDF) powder is an advanced fluoropolymer material engineered specifically as a high-performance binder for lithium-ion battery electrode fabrication. Functioning as a critical matrix component within composite cathode formulations, the polymer provides outstanding cohesive strength to bind active materials and conductive carbon additives into a unified, mechanically robust network. Its tailored molecular structure ensures complete dissolution in standard organic solvents such as N-methyl-2-pyrrolidone (NMP), enabling researchers and cell manufacturers to achieve homogeneous, defect-free electrode slurries ready for precision roll-to-roll or slot-die coating.

Designed to satisfy the stringent requirements of modern electrochemical systems, the binder demonstrates superior resistance to harsh organic carbonate electrolytes and elevated operating voltages. It maintains stable interfacial contact between active material particles—such as lithium iron phosphate (LiFePO4), nickel manganese cobalt oxides (NMC), and high-voltage spinels—and current collector substrates like aluminum foil. The material exhibits exceptional electrochemical passivity throughout repeated charge-discharge cycles, preventing premature electrode degradation, particle detachment, and capacity fade in high-rate energy storage devices.

Engineered for exceptional process repeatability, this fluoropolymer binder combines low moisture sensitivity with high thermal and chemical resilience. Its hydrophobic nature minimizes residual water introduction into battery cells, which is vital for preventing hydrofluoric acid generation and solid-electrolyte interphase (SEI) destabilization. Whether deployed in pilot-scale manufacturing, next-generation solid-state battery formulation, or academic electrochemical research, this material ensures dependable structural integrity and sustained electrochemical performance under demanding operational environments.

Key Features

  • Superior Interfacial Adhesion: Delivers strong mechanical anchoring between active material particles, conductive additives, and metallic current collector foils, effectively preventing delamination during high-tension calendering, winding, and repeated volumetric expansion cycles.
  • Broad Electrochemical Stability Window: Maintains complete chemical inertness across high operational voltages, resisting oxidative breakdown and degradation from aggressive non-aqueous liquid electrolytes and lithium salts.
  • Exceptional Thermal Resistance: Exhibits an initial thermal decomposition threshold between 375°C and 400°C (under air at 1% weight loss), easily withstanding high-temperature drying, vacuum baking, and aggressive cell cycling conditions.
  • Ultra-Low Moisture Uptake: Features a moisture absorption rate below 0.04% after 24 hours at 23°C, drastically reducing moisture-induced side reactions, electrolyte decomposition, and gas generation in hermetically sealed battery cells.
  • Optimal Solution Rheology: Dissolves smoothly in 1–2% N-methyl-2-pyrrolidone (NMP) solutions to produce stable, uniform slurry viscosities that prevent active mass sedimentation and guarantee uniform doctor-blade and slot-die coating.
  • Excellent Electrical Isolation: Provides a high volume resistivity of 1 × 10¹⁴ Ω·cm and surface resistivity of 1 × 10¹⁴ Ω/sq, preventing internal micro-shorting pathways while allowing conductive additives to govern electrical pathways.
  • Robust Flame Retardancy: Incorporates inherent self-extinguishing properties with a Limiting Oxygen Index (LOI) of 44%, contributing to improved passive thermal safety and abuse tolerance during catastrophic thermal events.
  • Controlled Melt Processing Characteristics: Displays a Melt Flow Index of 1.3 g/10 min (at 230°C, 21.6 kg), facilitating consistent melt compounding, electrospinning compatibility, and thermal consolidation processes when preparing composite matrices.

Applications

Application Description Key Benefit
Lithium-Ion Cathode Slurry Preparation Dissolved in NMP and blended with LiFePO4, NMC, LCO, or NCA active materials and conductive carbon black to form homogeneous coating slurries. Prevents slurry phase separation and ensures uniform active mass loading across metallic current collector substrates.
High-Rate Cell Electrode Calendering Used in high-power cylindrical, prismatic, and pouch cell electrodes subjected to intense mechanical roll-pressing and compaction forces. Mitigates microcracking and foil delamination during high-density calendering, preserving electrode microstructure.
Solid-State Battery Composite Cathodes Serves as a polymeric structural matrix holding solid electrolyte particles and high-capacity cathode chemistries in continuous contact. Accommodates mechanical stress and volumetric changes while sustaining intimate particle-to-particle ionic transport pathways.
Electrospun Polymeric Separator R&D Processed via electrospinning or phase inversion to generate porous non-woven membranes and separator coating layers. Delivers superior chemical resistance to organic solvents, high electrolyte wettability, and robust thermal shrinkage resistance.
Silicon-Graphite Anode Matrix Modification Blended into hybrid anode formulations to provide an elastic, electrochemically stable fluoropolymer binding network. Assists in dampening the extreme mechanical stress and delamination forces associated with silicon particle lithiation expansion.
Supercapacitor & Pseudocapacitor Electrodes Binds activated carbon, transition metal oxides, and MXenes to nickel foam or etched aluminum substrates for rapid energy discharge. Ensures stable low-impedance electrical contact without degrading under rapid electrostatic cycling and high current densities.

Technical Specifications

Parameter Category Specification Parameter Test Standard / Condition Value / Unit
Product Identification Base Product Identifier - CL33
Packaging Options Net Weight per Pack Sealed Moisture-Barrier Packaging 100 g / pack, 500 g / pack
Physical Properties Density ISO 1183 1.78 g/cm³
Water Absorption ISO 62 (Method 1, 24 h at 23°C) < 0.04%
Melt Flow Index (MFI) ASTM D 1238 (230°C, 21.6 kg) 1.3 g/10 min
Thermal Properties Thermal Stability (1% Weight Loss) TGA in Air 375 – 400 °C (707 – 752 °F)
Linear Thermal Expansion Coefficient ASTM D 696 120 – 140 × 10⁻⁶ K⁻¹
Thermal Conductance ASTM C 177 (at 23°C) 0.2 W/(m·K)
Specific Heat Capacity At 23°C & 100°C 1.2 – 1.6 J/(g·K)
Electrical Properties Surface Resistivity ASTM D 257 / DIN 53483 (Voltage <1 V, after 2 s -500 V, 23°C) 1 × 10¹⁴ Ω/sq
Volume Resistivity ASTM D 257 / DIN 53483 (Intensity = 10 mA, after 2 s, 23°C) 1 × 10¹⁴ Ω·cm
Fire Resistance Flammability Classification UL-94 Compliant Standard Class
Limiting Oxygen Index (LOI) ASTM D 2863 (Sheet thickness 3 mm) 44%

Why Choose This Product

  • Consistent Molecular Weight Distribution: Synthesized under tightly regulated polymerization protocols to guarantee narrow molecular weight dispersion, resulting in predictable dissolution rates in NMP and repeatable slurry viscosity batch after batch.
  • Superior Mechanical & Chemical Integrity: The semi-crystalline fluoropolymer backbone resists chemical attack from aggressive electrolyte solvents (EC, DMC, EMC, DEC) and suppresses active material detachment even across thousands of full depth-of-discharge cycles.
  • Low Impurity Profile for High-Voltage Reliability: Rigorously purified to remove residual monomers, metal ions, and volatile organics, preventing parasitic side reactions and unwanted gas evolution at high cathode working potentials.
  • Flexible Laboratory to Pilot Scalability: Supplied in convenient 100g and 500g hermetically sealed moisture-barrier packs, ensuring freshness for precise benchtop R&D while scaling seamlessly into pilot-line batch mixing.
  • Comprehensive Battery Formulation Expertise: Backed by specialized technical support covering slurry rheology optimization, mixing sequence best practices, and integration with complete coating, calendering, and cell assembly workflows.

Contact our technical team today to request a quote, discuss bulk packaging options, or receive tailored formulation guidance for your advanced battery research.

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Polyvinylidene Fluoride PVDF Powder Lithium Battery Cathode Binder

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